3 years ago

Structural Role of Isonicotinic Acid in U(VI), Np(VI), and Pu(VI) Complexes with TcO4–, ReO4–, and ClO4– Ions

Structural Role of Isonicotinic Acid in U(VI), Np(VI), and Pu(VI) Complexes with TcO4–, ReO4–, and ClO4– Ions
Grigory Andreev, Nina Budantseva, Aleksander Fedoseev
A series of new pertechnetate, perrhenate, and perchlorate compounds of hexavalent U, Np, and Pu were synthesized. Actinide (An) atoms were coordinated by 2 to 4 zwitterionic isonicotinic acid molecules. If two or three isonicotinic acid molecules are present in the surroundings of an An atom, TcO4 or ReO4 anions act as monodentate ligands. Otherwise, XO4 play the role of outer sphere anions. Electron and IR spectra of the compounds correlate with their crystal structure.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01611

DOI: 10.1021/acs.inorgchem.7b01611

You might also like
Never Miss Important Research

Researcher is an app designed by academics, for academics. Create a personalised feed in two minutes.
Choose from over 15,000 academics journals covering ten research areas then let Researcher deliver you papers tailored to your interests each day.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.