Angewandte Chemie - International Edition
Angewandte Chemie - International Edition
5 years ago

Intermolecular Formation of Two C−C Bonds across Olefins Enabled by Boron-Based Relay Strategies

Intermolecular Formation of Two C−C Bonds across Olefins Enabled by Boron-Based Relay Strategies
Denisa Hidasová, Ullrich Jahn
Smooth handoff in the relay: Vinyl boronates enable the direct addition of nucleophilic and electrophilic or nucleophilic and radical-generating carbon reagents across the double bond with retention of the valuable boronate group. The key to the success of this difficult twofold C−C bond-formation strategy is the initial relay of the nucleophilic addition to boron and the rearrangement of a 1,2-metalate rearrangement, shuttling it to carbon.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201705046

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