Inorganic Chemistry
Inorganic Chemistry
5 years ago

Single-Crystal to Single-Crystal Transformation of a Nonporous Fe(II) Metal–Organic Framework into a Porous Metal–Organic Framework via a Solid-State Reaction

Single-Crystal to Single-Crystal Transformation of a Nonporous Fe(II) Metal–Organic Framework into a Porous Metal–Organic Framework via a Solid-State Reaction
Pit Sippel, Maciej Grzywa, Dirk Volkmer, Serhiy Demeshko, Jonas K. H. Fischer, Stephan Reschke, Hans-Albrecht Krug von Nidda, Sebastian Spirkl
The SC to SC transformation of an iron(II) nonporous framework to a porous framework by a solid-state reaction is presented. The novel semiconducting framework is formed by tetrahedrally coordinated iron(II) centers and the 4,4′-bipyrazolate ligand.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01818

DOI: 10.1021/acs.inorgchem.7b01818

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