3 years ago

Vanadyl as a Stable Structural Mimic of Reactive Ferryl Intermediates in Mononuclear Nonheme-Iron Enzymes

Vanadyl as a Stable Structural Mimic of Reactive Ferryl Intermediates in Mononuclear Nonheme-Iron Enzymes
J. Martin Bollinger, Megan L. Matthews, Carsten Krebs, Alexey Silakov, Christopher J. Pollock, Ryan J. Martinie
The vanadyl ion can be used as a mimic of the key ferryl intermediate in Fe- and 2-oxoglutarate-dependent enzymes. The stability and electronic structure of the vanadyl ion allow structural characterization techniques not permitted by the native intermediate, opening new avenues for understanding catalysis in this important class of enzymes.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02113

DOI: 10.1021/acs.inorgchem.7b02113

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