3 years ago

Frustrated Lewis Pair Catalyzed S–H Bond Borylation

Frustrated Lewis Pair Catalyzed S–H Bond Borylation
Frédéric-Georges Fontaine, Hugo Boutin, Étienne Rochette
The frustrated Lewis pair (FLP) [NMe2-C6H4-BH2]2 is shown to catalyze the dehydrogenative borylation of thiols. The scope of the reaction, the experimental and computational investigation of the mechanism, and the application of the system to a one-pot Michael addition on α–β unsaturated carbonyl leading to the β sulfido ketone are reported.

Publisher URL: http://dx.doi.org/10.1021/acs.organomet.7b00346

DOI: 10.1021/acs.organomet.7b00346

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