3 years ago

Coordination Complexes of P-Containing Polycyclic Aromatic Hydrocarbons: Optical Properties and Solid-State Supramolecular Assembly

Coordination Complexes of P-Containing Polycyclic Aromatic Hydrocarbons: Optical Properties and Solid-State Supramolecular Assembly
Muriel Hissler, Christophe Lescop, Pierre-Antoine Bouit, Régis Réau, Rózsa Szűcs, László Nyulászi, François Riobé
A series of complexes including σ33-P-modified polycyclic aromatic hydrocarbon (PAH) as a ligand have been prepared showing that the ligand possesses a classical “phosphine-like” reactivity. The use of different metals (Pd(II), Cu(I), Re(I), Au(I)) having different coordination number allows tuning the optical properties of the complexes, which is dominated basically by the electronic transitions of the ligand itself. The study of the solid-state properties by mean of X-ray diffraction also shows that the combination of coordination chemistry and π-stacking interactions between the PAH ligand allows obtaining a great diversity of solid-state structures.

Publisher URL: http://dx.doi.org/10.1021/acs.organomet.6b00715

DOI: 10.1021/acs.organomet.6b00715

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