Mid-Gap States and Normal vs Inverted Bonding in Luminescent Cu+- and Ag+-Doped CdSe Nanocrystals

Journal of the American Chemical Society

4 years ago

Mid-Gap States and Normal vs Inverted Bonding in Luminescent Cu+- and Ag+-Doped CdSe Nanocrystals

Daniel R. Gamelin, Stijn O. M. Hinterding, Rachel Fainblat, Xiaosong Li, Heidi D. Nelson, Sidney E. Creutz

Mid-gap luminescence in copper (Cu⁺)-doped semiconductor nanocrystals (NCs) involves recombination of delocalized conduction-band electrons with copper-localized holes. Silver (Ag⁺)-doped semiconductor NCs show similar mid-gap luminescence at slightly (∼0.3 eV) higher energy, suggesting a similar luminescence mechanism, but this suggestion appears inconsistent with the large difference between Ag⁺ and Cu⁺ ionization energies (∼1.5 eV), which should make hole trapping by Ag⁺ highly unfavorable. Here, Ag⁺-doped CdSe NCs (Ag⁺:CdSe) are studied using time-resolved variable-temperature photoluminescence (PL) spectroscopy, magnetic circularly polarized luminescence (MCPL) spectroscopy, and time-dependent density functional theory (TD-DFT) to address this apparent paradox. In addition to confirming that Ag⁺:CdSe and Cu⁺:CdSe NCs display similar broad PL with large Stokes shifts, we demonstrate that both also show very similar temperature-dependent PL lifetimes and magneto-luminescence. Electronic-structure calculations further predict that both dopants generate similar localized mid-gap states. Despite these strong similarities, we conclude that these materials possess significantly different electronic structures. Specifically, whereas photogenerated holes in Cu⁺:CdSe NCs localize primarily in Cu(3d) orbitals, formally oxidizing Cu⁺ to Cu²⁺, in Ag⁺:CdSe NCs they localize primarily in 4p orbitals of the four neighboring Se^2– ligands, and Ag⁺ is not oxidized. This difference reflects a shift from “normal” to “inverted” bonding going from Cu⁺ to Ag⁺. The spectroscopic similarities are explained by the fact that, in both materials, photogenerated holes are localized primarily within covalent [MSe₄] dopant clusters (M = Ag⁺, Cu⁺). These findings reconcile the similar spectroscopies of Ag⁺- and Cu⁺-doped semiconductor NCs with the vastly different ionization potentials of their Ag⁺ and Cu⁺ dopants.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b01924

DOI: 10.1021/jacs.7b01924