Inorganic Chemistry
Inorganic Chemistry
5 years ago

Singly and Doubly N-Confused Calix[4]phyrin Organoplatinum(II) Complexes as Near-IR Triplet Sensitizers

Singly and Doubly N-Confused Calix[4]phyrin Organoplatinum(II) Complexes as Near-IR Triplet Sensitizers
Toshihiro Omagari, John Mack, Hiroyuki Furuta, Masatoshi Ishida, Susumu Fukatsu, Ryuji Hirosawa, Yuhsuke Yasutake, Tebello Nyokong, Yogesh Kumar Maurya, Poornenth Pushpanandan, Shigeki Mori
Structural modification of calix[4]phyrin by the N-confusion approach to influence the organometallic coordination environment provides red-shifted absorption and emission spectra in the near-IR region. The long-lived triplet state of the sensitizers enabled production of singlet oxygen with high efficiency.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02047

DOI: 10.1021/acs.inorgchem.7b02047

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