Inorganic Chemistry
Inorganic Chemistry
5 years ago

Structural Characterization of Am(III)- and Pu(III)-DOTA Complexes

Structural Characterization of Am(III)- and Pu(III)-DOTA Complexes
Philippe Moisy, Christoph Hennig, Marie-Claire Illy, Matthieu Audras, Laurence Berthon, Israel Zilbermann, Yeshayahu Ben-Eliyahu, Nicolas Martin, Armand Bettelheim, Thomas Dumas, Dominique Guillaumont, Claude Berthon, Sebastiano Cammelli, Yulia Moiseev
The complexation of DOTA with Am(III) and Pu(III) was investigated in solution. An intermediate species C1 complex [An(H2DOTA)(H2O)5+], which is formed instantaneously, evolves toward a C2 complex [An(DOTA)(H2O)−]. The variation of the logarithm of the concentration of the C1 species versus time was investigated by UV−visible spectrophotometry for Am-DOTA and Pu-DOTA species.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01666

DOI: 10.1021/acs.inorgchem.7b01666

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