Post-Mortem Analysis of Calendar-Aged 16 Ah NMC/Graphite Pouch Cells for EV Application

5 years ago

Post-Mortem Analysis of Calendar-Aged 16 Ah NMC/Graphite Pouch Cells for EV Application

Sylvie Genies, Michael Kasper, Niloofar Ghanbari, Frederic Aguesse, Thomas Waldmann, Margret Wohlfahrt-Mehrens, Amaia Iturrondobeitia, Emilie Bekaert

Application of Li-ion batteries for transportation not only requires long cycling life but also the preservation of the electrochemical performance during the resting period. For certain car usage this resting time could be predominant compared with the cycling activity and is referred to as calendar aging. To understand the aging mechanisms during calendar aging, an extensive post-mortem study was conducted on commercial 16 Ah NMC/graphite pouch cells stored at 5, 25, 45, and 60 °C. The post-mortem analyses were performed in parallel within three separate laboratories across Europe. They included visual inspection and structural and microstructural analysis along with a combination of analytical techniques to determine accurately the composition of positive (NMC) and negative (graphite) electrodes and the electrolyte. A direct correlation was established between the calendar-aging temperature and the degradation of the cells. The measurements revealed a severe deterioration phenomenon for the electrodes aged at 45 and 60 °C. These results are explained by the formation of a resistive interface on top of the negative electrodes due to a continuous and heterogeneous growth of a surface layer. Electrochemical impedance spectroscopy and electrochemical measurements confirm the resistance increase during cell degradation. At high temperatures, this occasionally leads to a Li deposition phenomenon. Nonetheless, we revealed that this degradation process does not affect the bulk structure of the materials but only the surface of the particles.

Publisher URL: http://dx.doi.org/10.1021/acs.jpcc.7b05416

DOI: 10.1021/acs.jpcc.7b05416