3 years ago

Carbohydrate-Functionalized 1,2,3-Triazolylidene Complexes for Application in Base-Free Alcohol and Amine Oxidation

Carbohydrate-Functionalized 1,2,3-Triazolylidene Complexes for Application in Base-Free Alcohol and Amine Oxidation
Martin Albrecht, Juan Olguín, René Pretorius
Triazole-derived N-heterocyclic carbene complexes of ruthenium(II) and iridium(III) containing a carbohydrate functionality on the carbene were prepared. Deprotection of the carbohydrate was accomplished at the iridium complex and produced complexes that were catalytically more active in acceptorless alcohol and amine oxidation compared to the carbohydrate-protected anaolgues, indicating a beneficial role of the unprotected carbohydrate functional group.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01899

DOI: 10.1021/acs.inorgchem.7b01899

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