Chemical Science
Chemical Science
5 years ago

(Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles

(Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles
Max M. Hansmann, Rodolphe Jazzar, David A. Ruiz, Liu (Leo) Liu, Guy Bertrand
Although BH3 simply coordinates the endocyclic P of (phospholidino)phosphaketene 1Dipp, the bulkier B(C6F5)3 gives rise to a zwitterionic diphosphirenium, which is a novel type of 2[small pi]-electron aromatic system as shown by the calculated NICS values.

Publisher URL: http://feeds.rsc.org/~r/rss/SC/~3/97WlEj5RHjI/C7SC00300E

DOI: 2017/SC/C7SC00300E

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