Chemistry of Materials
Chemistry of Materials
5 years ago

Assembly–Disassembly–Organization–Reassembly Synthesis of Zeolites Based on cfi-Type Layers

Assembly–Disassembly–Organization–Reassembly Synthesis of Zeolites Based on cfi-Type Layers
Paul S. Wheatley, Samuel A. Morris, Russell E. Morris, Petr Nachtigall, Samantha E. Russell, Jiři Čejka, Alexandra M. Z. Slawin, Alvaro Mayoral, Daniel S. Firth, Miroslav Položij, Daniel M. Dawson, Maksym Opanasenko
The hydrothermal synthesis of a zeolite with properties suitable for use in the assembly–disassembly–organization–reassembly (ADOR) process was designed, and a zeolite called SAZ-1 was successfully prepared. This zeolite was then used as a parent in the ADOR process, and two new daughter zeolites, IPC-15 and IPC-16, were prepared. The X-ray powder diffraction patterns of the new zeolites match well with those predicted using computational methods. The three materials form an isoreticular series with decreasing pores size from 14-ring to 12-ring to 10-ring.

Publisher URL: http://dx.doi.org/10.1021/acs.chemmater.7b01181

DOI: 10.1021/acs.chemmater.7b01181

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