3 years ago

Tricyanomethane and Its Ketenimine Tautomer: Generation from Different Precursors and Analysis in Solution, Argon Matrix, and as a Single Crystal

Tricyanomethane and Its Ketenimine Tautomer: Generation from Different Precursors and Analysis in Solution, Argon Matrix, and as a Single Crystal
Tony Stüker, Tobias Rüffer, Klaus Banert, Sebastian Riedel, Madhu Chityala, Heinrich Lang, Helmut Beckers, Manfred Hagedorn
Tricyanomethane and its ketenimine tautomer were not simultaneously observed in the studies described by K. Banert, H. Beckers, and co-workers in their Communication (DOI: 10.1002/anie.201704561). Whereas the latter species was detected after irradiation of an appropriate vinyl azide in argon matrix, photolysis or thermolysis of the same precursor in solution led to cyanoform with a pyramidal structure, which can also be generated from tricyanomethanide. Single crystals of pure tricyanomethane were found to be surprisingly stable.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201706518

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