Organic Letters
Organic Letters
4 years ago

Methods for the Synthesis of Substituted Azetines

Methods for the Synthesis of Substituted Azetines
Dorian Didier, Arif Music, Yu Min Kiw, Geoffrey Haas, Michael Eisold, Andreas N. Baumann
Spurred on by the recent emerging interest from the chemical community for unsaturated four-membered heterocycles, an unprecedented approach to nitrogen-containing four-membered rings has been designed. 3,4-Disubstituted 2-azetines were synthesized from commercially available substrates, allowing for a straightforward access to a new library of chiral functionalized azetidines and amino alcohols. This original approach was applied to efficiently prepare functionalized azobenzenes, an emerging class of molecules with a large potential in photopharmacology.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b02847

DOI: 10.1021/acs.orglett.7b02847

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