Structural insights into the multinuclear speciation of tetravalent cerium in the tri-n-butyl phosphate-n-dodecane solvent extraction system

5 years ago

Structural insights into the multinuclear speciation of tetravalent cerium in the tri-n-butyl phosphate-n-dodecane solvent extraction system

Shanna L. Estes, Ross J. Ellis, Mrinal K. Bera, Mark R. Antonio

Macroscopic phase behaviors in the liquid-liquid extraction are explained by microscopic, reverse micellar fluid structures containing tetranuclear Ce(IV) clusters revealed by use of X-ray spectroscopy and scattering of the light and dense organic phases.

Publisher URL: http://feeds.rsc.org/~r/rss/CP/~3/z_vqqeX95JU/C7CP03350H

DOI: 2017/CP/C7CP03350H

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