5 years ago

Zinc Acetate-Promoted Buchwald–Hartwig Couplings of Heteroaromatic Amines

Zinc Acetate-Promoted Buchwald–Hartwig Couplings of Heteroaromatic Amines
Gregory L. Beutner, Jacob Janey, Martin D. Eastgate, Daniel S. Treitler, Rajaram Ayothiraman, Rajappa Vaidyanathan, Eric M. Simmons, Prantik Maity, Sundaramurthy Rangaswamy
Zinc salts have been shown to promote the Buchwald–Hartwig coupling of azaindoles and azaindazoles with heteroaryl chlorides to provide the corresponding 1-aryl-1H-azaindoles and 1-aryl-1H-azaindazoles. The substrate scope and mechanistic aspects of this reaction were explored.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b01101

DOI: 10.1021/acs.joc.7b01101

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