Journal of Physical Chemistry C
Journal of Physical Chemistry C
5 years ago

Faraday Effect in Stacks of Aromatic Molecules

Faraday Effect in Stacks of Aromatic Molecules
Thierry Verbiest, Benoît Champagne, André Persoons, Vincent Liégeois, Orian Louant
The effects of stacking aromatic units on the Verdet constant are analyzed by employing quantum chemistry calculations and are compared to the effects of oligomerization. Building stacked oligomers leads to enhanced Verdet constants, but still smaller than in the corresponding linear oligomers. Further enhancements appear when going from simple to fused-ring polyaromatic compounds.

Publisher URL: http://dx.doi.org/10.1021/acs.jpcc.7b04177

DOI: 10.1021/acs.jpcc.7b04177

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