4 years ago

The Suzuki–Miyaura Coupling of Nitroarenes

The Suzuki–Miyaura Coupling of Nitroarenes
Takanori Miyazaki, Yoshiaki Nakao, Rong-Lin Zhong, Masahiro Nagaoka, Shigeyoshi Sakaki, Myuto Kashihara, M. Ramu Yadav
Synthesis of biaryls via the Suzuki–Miyaura coupling (SMC) reaction using nitroarenes as an electrophilic coupling partners is described. Mechanistic studies have revealed that the catalytic cycle of this reaction is initiated by the cleavage of the aryl–nitro (Ar–NO2) bond by palladium, which represents an unprecedented elemental reaction.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b03159

DOI: 10.1021/jacs.7b03159

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.