3 years ago

The Suzuki–Miyaura Coupling of Nitroarenes

The Suzuki–Miyaura Coupling of Nitroarenes
Takanori Miyazaki, Yoshiaki Nakao, Rong-Lin Zhong, Masahiro Nagaoka, Shigeyoshi Sakaki, Myuto Kashihara, M. Ramu Yadav
Synthesis of biaryls via the Suzuki–Miyaura coupling (SMC) reaction using nitroarenes as an electrophilic coupling partners is described. Mechanistic studies have revealed that the catalytic cycle of this reaction is initiated by the cleavage of the aryl–nitro (Ar–NO2) bond by palladium, which represents an unprecedented elemental reaction.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b03159

DOI: 10.1021/jacs.7b03159

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