4 years ago

Cover Picture: Preparation and Characterization of Group 13 Cyanides (Chem. Eur. J. 38/2017)

Cover Picture: Preparation and Characterization of Group 13 Cyanides (Chem. Eur. J. 38/2017)
Monica Vasiliu, Piyush Deokar, Karl O. Christe, David A. Dixon, Trent H. Stein, Ralf Haiges
New binary Group 13 cyanides were prepared from the corresponding metal trifluorides [MF3] (M = Ga, In, Tl) by fluoride–cyanide exchange reactions with Me3SiCN in the presence of stoichiometric amounts of [PPh4][CN] or 2,2’-bipyridine in acetonitrile solution. Although the reaction of the metal trifluorides with Me3SiCN in acetonitrile resulted in the recovery of the starting materials, the reaction of [MF3] with Me3SiCN in pyridine (py) solution resulted in the formation of the pyridine adducts [(py)2Ga(CN)3], [(py)3In(CN)3], and [(py)2Tl(CN)3. More information can be found in the Full Paper by R. Haiges et al. on page 9054.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201701747

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