Chemistry - A European Journal
Chemistry - A European Journal
5 years ago

Back Cover: Synthesis, Structural Characterization, and Crystal Packing of the Elusive Pentachlorinated Azafullerene C59NCl5 (Chem. Eur. J. 38/2017)

Back Cover: Synthesis, Structural Characterization, and Crystal Packing of the Elusive Pentachlorinated Azafullerene C59NCl5 (Chem. Eur. J. 38/2017)
Andreas Hirsch, Frank Hampel, Dmitry I. Sharapa, Kateryna Roshchyna, Johannes Holzwarth, Konstantin Yu. Amsharov
The azafullerene pentachloride C59NCl5 obtained by high temperature halogenation of (C59N)2 displays unprecedented and effective supramolecular bonding to the fullerene “surface”. The cumulative effect of five chloro-π interactions leads to an effective 1D host–guest stacking in the solid state. The pentachlorinated addition pattern serves as a “receptor” of the bowl-shaped corannulene fragment and thus appears to be prospective for possible recognition of fullerenes and related geodesic PAH structures. More information can be found in the Communication by K. Yu. Amsharov, A. Hirsch et al. on page 9014.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201701558

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