3 years ago

Unexpected Ge–Ge Contacts in the Two-Dimensional Ge4Se3Te Phase and Analysis of Their Chemical Cause with the Density of Energy (DOE) Function

Unexpected Ge–Ge Contacts in the Two-Dimensional Ge4Se3Te Phase and Analysis of Their Chemical Cause with the Density of Energy (DOE) Function
Merlin Müller, Matthias Wuttig, Richard Dronskowski, Min Zhu, Philipp M. Konze, Antonio M. Mio, Oana Cojocaru-Mirédin, Simon Steinberg, Michael Küpers, Stefan Maintz, Joachim Mayer, Martina Luysberg
Unexpected Ge–Ge interactions were found in “two-dimensional” Ge4Se3Te as reported by R. Dronskowski et al. in their Communication (DOI: 10.1002/anie.201612121). The layered material was crystallized using chemical vapor deposition and then characterized for the first time. Its electronic structure and the chemical cause of the Ge–Ge interactions were examined by chemical bonding analysis and the newly introduced density of energy (DOE) function.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201706616

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