3 years ago

Regioselective and Switchable meso-Aminations and Couplings of 5,15-Diarylchlorins

Regioselective and Switchable meso-Aminations and Couplings of 5,15-Diarylchlorins
Yi Yuan, Yu-Hao Qiu, Qi Cheng, Ying-Chun Chen, Qin Ouyang, Li Shuai, Sheng-Lin Luo
Controllable chemo- and regiodivergent amination reactions of anilines and chlorins are accomplished by employing different oxidants and substrates, constructing aminated chlorin monomers and dimers with high structural diversity. Importantly, besides preferential 20-meso-position, the oxidative amination was also realized at the inactive 10-meso-position by using phenyliodine bis(trifluoroacetate) (PIFA) and gold(III)-based reagents.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b01739

DOI: 10.1021/acs.orglett.7b01739

You might also like
Never Miss Important Research

Researcher is an app designed by academics, for academics. Create a personalised feed in two minutes.
Choose from over 15,000 academics journals covering ten research areas then let Researcher deliver you papers tailored to your interests each day.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.