3 years ago

N-Heterocyclic carbene-stabilised arsinidene (AsH)

N-Heterocyclic carbene-stabilised arsinidene (AsH)
Michael Weinhart, Alexander Hinz, Jose M. Goicoechea, Matthias Tamm, Adinarayana Doddi, Dirk Bockfeld, Manfred Scheer
N-Heterocyclic carbene adducts of the parent arsinidene (AsH) were prepared by two different synthetic routes, either by reaction of As(SiMe3)3 with 2,2-difluoroimidazolines followed by desilylation or by reaction of [Na(dioxane)3.31][AsCO] with imidazolium chlorides.

Publisher URL: http://feeds.rsc.org/~r/rss/CC/~3/F4W3SnjqNIw/C7CC02628E

DOI: 2017/CC/C7CC02628E

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