Dynamic Colloidal Molecules Maneuvered by Light-Controlled Janus Micromotors

5 years ago

Dynamic Colloidal Molecules Maneuvered by Light-Controlled Janus Micromotors

Jianguo Guan, Yirong Gao, Leilei Xu, Wei Li, Shengping Che, Yizheng Feng, Fangzhi Mou

In this work, we propose and demonstrate a dynamic colloidal molecule that is capable of moving autonomously and performing swift, reversible, and in-place assembly dissociation in a high accuracy by manipulating a TiO₂/Pt Janus micromotor with light irradiation. Due to the efficient motion of the TiO₂/Pt Janus motor and the light-switchable electrostatic interactions between the micromotor and colloidal particles, the colloidal particles can be captured and assembled one by one on the fly, subsequently forming into swimming colloidal molecules by mimicking space-filling models of simple molecules with central atoms. The as-demonstrated dynamic colloidal molecules have a configuration accurately controlled and stabilized by regulating the time-dependent intensity of UV light, which controls the stop-and-go motion of the colloidal molecules. The dynamic colloidal molecules are dissociated when the light irradiation is turned off due to the disappearance of light-switchable electrostatic interaction between the motor and the colloidal particles. The strategy for the assembly of dynamic colloidal molecules is applicable to various charged colloidal particles. The simulated optical properties of a dynamic colloidal molecule imply that the results here may provide a novel approach for in-place building functional microdevices, such as microlens arrays, in a swift and reversible manner.

Publisher URL: http://dx.doi.org/10.1021/acsami.7b05794

DOI: 10.1021/acsami.7b05794