Thiosemicarbazone organocatalysis: tetrahydropyranylation and 2-deoxygalactosylation reactions and kinetics-based mechanistic investigation

5 years ago

Thiosemicarbazone organocatalysis: tetrahydropyranylation and 2-deoxygalactosylation reactions and kinetics-based mechanistic investigation

Line M. Langhorn, Olivia M. Akselsen, Michael Pittelkow, Bjarne E. Nielsen, Dennis Larsen

Thiosemicarbazones are introduced as a new class of highly tunable and efficient organocatalysts. We showcase this by studies of the tetrahydropyranylation reaction, where insights to the mechanism was achieved by a double Hammett analysis of both the substrate and the catalyst.

Publisher URL: http://feeds.rsc.org/~r/rss/SC/~3/ggmrozlzdN8/C7SC03366D

DOI: 2017/SC/C7SC03366D

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