Tetrahedron
Tetrahedron
5 years ago

The Chan-Evans-Lam N-arylation of phosphonic/phosphinic amides

The Chan-Evans-Lam N-arylation of phosphonic/phosphinic amides
A stoichiometric copper(II)-mediated arylation protocol of phosphinamides and phosphonamides was herein demonstrated. Various unreported N-aryl phosphinamides and phosphonamides were successfully prepared through Chan-Evans-Lam reaction with high efficiency (up to 88% yields) and good functional groups tolerance (30 examples) in the absence of any ligands or co-catalysts.

Publisher URL: www.sciencedirect.com/science

DOI: S0040402017306476

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