Organic and Biomolecular Chemistry
Organic and Biomolecular Chemistry
5 years ago

C-ON bond homolysis of alkoxyamines: when too high polarity is detrimental

C-ON bond homolysis of alkoxyamines: when too high polarity is detrimental
Valerie Roubaud, Sylvain R. A. Marque, Paulin Nkolo, Gerard Audran, Paul Bremond, Raphael Bikanga
In this article, previous multi-parameter linear relationships are amended using a parabolic model to describe the effect of EWGs in the alkyl fragment of alkoxyamines on the homolysis rate constant kd.

Publisher URL: http://feeds.rsc.org/~r/rss/OB/~3/X7c_KnkC0A0/C7OB01312D

DOI: 2017/OB/C7OB01312D

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