5 years ago

Deoxygenation of Ethers To Form Carbon–Carbon Bonds via Nickel Catalysis

Deoxygenation of Ethers To Form Carbon–Carbon Bonds via Nickel Catalysis
Zhang-Jie Shi, Zhi-Chao Cao
In this article a successful protocol was developed to construct carbon–carbon bonds by the extrusion of the O atom of ethers via nickel catalysis in the presence of reductants. This methodology is featured as a highly economic route to construct sp3–sp3 C–C bonds through dual C–O activation of ethers with good functional group tolerance.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b02326

DOI: 10.1021/jacs.7b02326

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