3 years ago

Exploring the Inverse Magnetocaloric Effect in Discrete MnII Dimers

Exploring the Inverse Magnetocaloric Effect in Discrete MnII Dimers
Ming-Liang Tong, Yan-Cong Chen, Wen-Bin Chen, Quan-Wen Li, Si-Guo Wu, Yang Liu, Jun-Liang Liu
The inverse magnetocaloric effect (IMCE) in molecular solids is explored for two antiferromagnetically coupled MnII dinuclear complexes. Magnetic studies reveal that both of them demonstrate the IMCE with negative magnetic entropy changes (−ΔSM = −3.5 J kg–1 K–1), which are in line with an analytic function derived from the quantized phenomenological model proposed in this work.

Publisher URL: http://dx.doi.org/10.1021/acs.jpcc.7b08271

DOI: 10.1021/acs.jpcc.7b08271

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