5 years ago

Frontispiece: Nitrene Radical Intermediates in Catalytic Synthesis

Frontispiece: Nitrene Radical Intermediates in Catalytic Synthesis
Bas de Bruin, Petrus F. Kuijpers, Sven Schneider, Jarl Ivar van der Vlugt
Nitrene radical complexes are reactive intermediates with intriguing electronic structures, and are best described as “nitrogen-centered radicals”. They are important intermediates in a variety of “nitrene transfer” reactions, such as aziridination and C−H amination. The Concept article by B. de Bruin et al. on page 13819 ff. is focused on their electronic structure, involvement in catalysis and highlights the important developments in the field.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201785661

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