4 years ago

Mechanochemical Synthesis of Phosphazane-Based Frameworks

Mechanochemical Synthesis of Phosphazane-Based Frameworks
Ying Sim, Yongxin Li, Felipe García, Rakesh Ganguly, Yan X. Shi
Mechanochemistry is emerging as a powerful solvent-free approach to chemical synthesis. Examples of mechanochemical methodologies in the synthesis of main-group compounds are few and far between. It is shown that ball-milling enables the solvent-free synthesis of a range of phosphazane frameworks with a broad substrate scope, yielding new acyclic and macrocyclic species. Fast, selective and high-yielding product generation from poorly soluble starting materials demonstrates the potential of mechanochemistry as a powerful alternative to solution-based methods in synthetic main-group chemistry. More information can be found in the Full Paper by F. García et al. (DOI: 10.1002/chem.201701619).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201702832

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