Tetrahedron
Tetrahedron
5 years ago

Synthesis of P(O)-S organophosphorus compounds by dehydrogenative coupling reaction of P(O)H compounds with aryl thiols in the presence of base and air

Synthesis of P(O)-S organophosphorus compounds by dehydrogenative coupling reaction of P(O)H compounds with aryl thiols in the presence of base and air
The synthesis method of P(O)-S organophosphorus compounds by dehydrogenative coupling reaction of P(O)H compounds and aryl thiols was developed. The reaction was carried in the presence of a base and air, and exhibited good characters such as metal-free, mild reaction temperature, excellent substrate tolerance and with moderate to good yields. A plausible mechanism was proposed.

Publisher URL: www.sciencedirect.com/science

DOI: S0040402017304064

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