Frontispiece: Direct Nucleophilic Substitution Reaction of Cage B−H Bonds by Grignard Reagents: A Route to Regioselective B4-Alkylation of o-Carboranes

Angewandte Chemie - International Edition

5 years ago

Frontispiece: Direct Nucleophilic Substitution Reaction of Cage B−H Bonds by Grignard Reagents: A Route to Regioselective B4-Alkylation of o-Carboranes

Zuowei Xie, Cen Tang, Jiji Zhang

Carborane FunctionalizationIn their Communication on page 8642 ff., Z. Xie and co-workers report the first nucleophilic substitution reaction of cage B−H bonds in o-carboranes by Grignard reagents in the absence of any transition metals.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201783061

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