4 years ago

Catalyst Controlled Regiodivergent Arylboration of Dienes

Catalyst Controlled Regiodivergent Arylboration of Dienes
Stephen R. Sardini, M. Kevin Brown
A method for the regiodivergent arylboration of dienes is presented. These reactions allow for the formation of a diverse range of synthetically versatile products from simple precursors. Through mechanistic studies, these reactions likely operate by initial addition of a Cu–Bpin complex across the diene followed by Pd-catalyzed cross coupling with an aryl halide or pseudohalide.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b05477

DOI: 10.1021/jacs.7b05477

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